American Journal of Renewable and Sustainable Energy
Articles Information
American Journal of Renewable and Sustainable Energy, Vol.4, No.2, Jun. 2018, Pub. Date: Jul. 20, 2018
Indocyanine Green as a Sensitizer for Dye-Sensitized Solar Cell
Pages: 33-39 Views: 2208 Downloads: 891
Authors
[01] Adrian Jones, Center for Nanotechnology, Department of Natural Sciences, Coppin State University, Baltimore, USA.
[02] William Ghann, Center for Nanotechnology, Department of Natural Sciences, Coppin State University, Baltimore, USA.
[03] Jamal Uddin, Center for Nanotechnology, Department of Natural Sciences, Coppin State University, Baltimore, USA.
Abstract
We report in this paper the photophysical characterization of Indocyanine green (ICG) dye and its application in dye sensitized solar cells. ICG is a water soluble, tricarbocyanine dye which forms noncovalent fluorescent complexes with proteins and as a result has been used for medical diagnostics through fluorescence imaging technologies. The ICG along with another cyanine dye (Cy 4) was used in this study. The photophysical studies performed included UV-vis, fluorescence, and lifetime measurements. The Cy 4 has two hydroxyl groups which serve as anchoring groups facilitating the attachment of the dye to the titanium dioxide nanocrystalline surface. They are therefore well suited for use as sensitizing dye in dye sensitized solar cells. There was no significant difference in the photophysical properties of the two different dyes deployed in the studies. The samples were also characterized used Field Emission Scanning Electron Microscopy. The current and voltage characteristics were measured and the short circuit current, open circuit voltage, fill factor, and the solar-to-electric power efficiency, subsequently determined. The efficiency of the ICG was 0.08% whiles that of Cy 4 was 0.11%.
Keywords
Cyanine, Dye, Indocyanine Green, Solar Cell, Titanium Dioxide, DSSC
References
[01] B. O'Regan and M. Grätzel, "A Low-Cost, High-Efficiency Solar Cell Based on Dye-Sensitized Colloidal TiO2 Films," Nature 353, 737 (1991).
[02] Mathew, S. et al. Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers. Nat. Chem. 6, 242–247 (2014).
[03] Michael Grätzel, Dye-sensitized solar cells, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Volume 4, Issue 2, 2003, Pages 145-153, ISSN 1389-5567, http://dx.doi.org/10.1016/S1389-5567(03)00026-1.
[04] Sugathan, V., John, E. & Sudhakar, K. Recent improvements in dye sensitized solar cells: A review. Renew Sust Energ Rev 52, 54–64 (2015).
[05] Gong, J., Liang, J., Sumathy, K. Review on dye-sensitized solar cells (DSSCs): Fundamental concepts and novel materials, Renewable and Sustainable Energy Reviews, 16 (8), 5848-5860 (2012).
[06] Hagfeldt, A., Boschloo, G., Sun, L., Kloo, L., and Pettersson, H., Dye-Sensitized Solar Cells. Chemical Reviews 110 (11), 6595-6663 (2010).
[07] 10. Meyer, G. J. The 2010 Millennium Technology Grand Prize: Dye-Sensitized Solar Cells. ACS Nano. 4, 4337–4343 (2010).
[08] Narayan, M. R. Review: Dye sensitized solar cells based on natural photosensitizers. Renew Sust Energ Rev 16, 208–215 (2012).
[09] Hao, S., Wu, J., Huang, Y. & Lin, J. Natural dyes as photosensitizers for dye-sensitized solar cell. Sol. Energ 80, 209–214 (2006).
[10] Shalini, S., Balasundara prabhu, R., Prasanna, S., Mallick, T. K. & Senthilarasu, S. Review on natural dye sensitized solar cells: Operation, materials and methods. Renew Sust Energ Rev 51, 1306–1325 (2015).
[11] Bahadur, K. I., Jyoti, N. J., Kumar, M. P. & Suman, C. Dye-Sensitized Solar cell using extract of Punica Granatum L. Pomegranate (Bedana) as a Natural Sensitizer. Research of J. Chem. Sci. 2, 81–83 (2012).
[12] Hug, H., Bader, M., Mair, P. & Glatzel, T. Biophotovoltaics: Natural pigments in dye-sensitized solar cells Appl. Energy 115, 216–225 (2014).
[13] Ludin, N. A. et al. Review on the development of natural dye photosensitizer for dye-sensitized solar cells. Renew Sust Energ. Rev. 31, 386–396 (2014).
[14] Ghann, W., Chavez-Gil, T., Goede, C. I., Kang, H., Khan, S., Sobhi, H., Nesbitt, F. and Uddin, J. (2017) Photophysical, Electrochemical and Photovoltaic Properties of Porphyrin-Based Dye Sensitized Solar Cell. Advances in Materials Physics and Chemistry, 7, 148-172. https://doi.org/10.4236/ampc.2017.75013
[15] Birel, Ö., Nadeem, S. & Duman, H. Porphyrin-Based Dye-Sensitized Solar Cells (DSSCs): A Review J Fluoresc (2017) 27: 1075. https://doi.org/10.1007/s10895-017-2041-2
[16] Adineh, M., Tahay, P., Shahrjerdi, A. et al. Dye-sensitized solar cells, based on electrochemically functionalized porphyrins J IRAN CHEM SOC (2016) 13: 1357. https://doi.org/10.1007/s13738-016-0850-x
[17] Ye et. al., Recent advances in quantum dot-sensitized solar cells: insights into photoanodes, sensitizers, electrolytes and counter electrodes. Sustainable Energy Fuels, 2017, 1, 1217-1231.
[18] Jun, H. K., Careem, M. A. and Arof, A. K. Quantum dot-sensitized solar cells—perspective and recent developments: A review of Cd chalcogenide quantum dots as sensitizers, Renewable and Sustainable Energy Reviews, 22, 148-167 (2013).
[19] William Ghann, Hyeonggon Kang, Edward Emerson, Jiyoung Oh, Tulio Chavez-Gil, Fred Nesbitt, Richard Williams, Jamal Uddin, Photophysical properties of near-IR cyanine dyes and their application as photosensitizers in dye sensitized solar cells, In Inorganica Chimica Acta, Volume 467, 2017, Pages 123-131, ISSN 0020-1693, https://doi.org/10.1016/j.ica.2017.08.001.
[20] Wu, W. Guo, F., Li, J., He, J. Hua, J., New fluoranthene-based cyanine dye for dye-sensitized solar cells. Synthetic Metals, 160 (9–10) 1008-1014 (2010).
[21] Wu, WJ., Zhan, WH., Hua, JL. et al. Res. Chem. Intermed. (2008) 34: 241. https://doi.org/10.1163/156856708783623438
[22] Ma, X., Hua, J., Wu, W., Jin, Y., Meng, F., Zhan, W., Tian, H., A high-efficiency cyanine dye for dye-sensitized solar cells. Tetrahedron, 2008, 64 (2), 345-350.
[23] Ehret, A. Stuhl, L and, Spitler, M. T., Spectral Sensitization of TiO2 Nanocrystalline Electrodes with Aggregated Cyanine Dyes, The Journal of Physical Chemistry B 2001 105 (41), 9960-9965.
[24] Kobasa, I. M. & Kondrat’eva, I. V. Theor Exp Chem, Dark and photochemical reactions between cyanine dye with two conjugated chromophores and titanium dioxide (2008) 44: 80. https://doi.org/10.1007/s11237-008-9017-x
[25] Yuan B, Chen N, Zhu Q. Emission and absorption properties of indocyanine green in Intralipid solution. Journal of biomedical optics. 2004; 9 (3): 497-503. doi: 10.1117/1.1695411.
[26] Gerega A, Zolek N, Soltysinski T, et al; Wavelength-resolved measurements of fluorescence lifetime of indocyanine green. J. Biomed. Opt. 0001; 16 (6): 067010-067010-9. doi: 10.1117/1.3593386.
[27] Boni L, David G, Mangano A, et al. Clinical applications of indocyanine green (ICG) enhanced fluorescence in laparoscopic surgery. Surgical Endoscopy. 2015; 29 (7): 2046-2055. doi: 10.1007/s00464-014-3895-x.
[28] Ghann, W., Sobhi, H., Kang, H., Chavez-Gil, T., Nesbitt, F. and Uddin, J. (2017) Synthesis and Characterization of Free and Copper (II) Complex of N, N′-Bis(Salicylidene) Ethylenediamine for Application in Dye Sensitized Solar Cells. Journal of Materials Science and Chemical Engineering, 5, 46-66. doi: 10.4236/msce.2017.56005.
[29] William Ghann, Aunik Rahman, Anis Rahman & Jamal Uddin, Interaction of Sensitizing Dyes with Nanostructured TiO2 Film in Dye-Sensitized Solar Cells Using Terahertz Spectroscopy. Scientific Report. 6, 30140; doi: 10.1038/srep30140 (2016).
[30] Amadi, L. et al. Creation of Natural Dye Sensitized Solar Cell by Using Nanostructured Titanium Oxide. Nanosci. Nanoeng. 3, 25–35 (2015).
[31] Ghann et. al., Fabrication, Optimization and Characterization of Natural Dye Sensitized Solar Cell. Scientific Report, 7, 41470; doi: 10.1038/srep41470 (2017).
[32] Lee H, Berezin MY, Henary M, Strekowski L, Achilefu S., Fluorescence lifetime properties of near-infrared cyanine dyes in relation to their structures. J Photochem Photobiol A Chem. 2008; 200 (2-3): 438-444.
[33] Berezin, M. Y., & Achilefu, SFluorescence Lifetime Measurements and Biological Imaging. Chemical Reviews, 110 (5), 2641–2684. (2010). http://doi.org/10.1021/cr900343z
[34] Gerega et al. Wavelength-resolved measurements of fluorescence lifetime of indocyanine green. Journal of biomedical optics. 16 (6), 067010, (2011). 10.1117/1.3593386.
[35] Wang, Q., Moser, J-E., & Grätzel, M. Electrochemical Impedance Spectroscopic Analysis of Dye-Sensitized Solar Cells. The Journal of Physical Chemistry B 2005 109 (31), 14945-14953.
[36] Sarker, S., Ahammad, A. S., Seo, H. W., & Kim, D. M. “Electrochemical Impedance Spectra of Dye-Sensitized Solar Cells: Fundamentals and Spreadsheet Calculation,” International Journal of Photoenergy, 2014, 851705, 1-14. doi: 10.1155/2014/851705.
600 ATLANTIC AVE, BOSTON,
MA 02210, USA
+001-6179630233
AIS is an academia-oriented and non-commercial institute aiming at providing users with a way to quickly and easily get the academic and scientific information.
Copyright © 2014 - American Institute of Science except certain content provided by third parties.