Articles Information
Chemistry Journal, Vol.1, No.4, Aug. 2015, Pub. Date: Jun. 2, 2015
Studies on Adsorption Capacity of Zeolite for Removal of Chemical and Bio-Chemical Oxygen Demands
Pages: 139-143 Views: 4995 Downloads: 2529
Authors
[01]
Milan M. Lakdawala, Chemistry Department, S. P. T. Arts and Science College, Godhra, Gujarat, India.
[02]
Yogesh S. Patel, Chemistry Department, Government Science College, Gandhinagar, Gujarat, India.
Abstract
Pollution of soil and water by hazardous chemicals excreted from industries has become serious environmental concern. From the environmental and aesthetic point of view, removal of pollutants from effluent is extremely essential. Due to the organic loads, the treatment of removal efficiency is rather challenging by conventional methods. Therefore, adsorption process is found to be the most efficient method. Numerous approaches have been studied for the development of low–cost adsorbents. Zeolite is found to be the most effective and economical adsorbent. In the present study, zeolite with specific surface area of 2762.47cm2/gm was used for removal of biochemical oxygen demand from the combined waste water of sugar industry. The combined waste water of sugar industry is treated with different doses (i.e. 5 gm/L, 10 gm/L, 40 gm/L, 80 gm/L, 120 gm/L, 160 gm/L, 200 gm/L) of zeolite. With increase in dosage of zeolite, considerable decrease in biochemical oxygen demand was observed.
Keywords
Zeolite, Adsorption, Freundlich Isotherm, Langmuir Isotherm
References
[01]
Bansoda RR, Losso JN, Marshall WE, Rao, RM, Portier RJ (2004) Pecan shell-based granular activated carbon for treatment of chemical oxygen demand (COD) in municipal wastewater. J. Bioresour. Tech. 94:129–135.
[02]
Ahmedna M, Marshall WE, Rao RM (2000) Production of granular activated carbons from selected agricultural by-products and evaluation of their physical, chemical and adsorption properties. J. Bioresour. Tech. 71:113–123.
[03]
Pala A, Tokat E (2000) Color removal from cotton textile industry wastewater in an activated sludge system with various additives. J Water Res 36:2920–2925.
[04]
Guohua C (2004) Electrochemical technologies in wastewater treatment. Sep Purif Tech 38(1):11–41.
[05]
Martinez NS, Fernandez JF, Segura XF, Ferrer AS (2003) Pre-oxidation of an extremely polluted industrial wastewater by the Fenton’s reagent. J. Hazard. Mater. B101:315–322.
[06]
Hung CM, Lou JC, Lin CH (2003) Removal of ammonia solutions used in catalytic wet oxidation processes. J. Chemosphere. 52:989–995.
[07]
Xiong Y, Strunk P, Xia H, Zhu X, Karlsson H (2000) Treatment of dye wastewater contain acidic orange II using a cell with three-phase three dimensional electrodes. J. Water Res. 35(17):4226–4230.
[08]
Gogate PR, Pandit AB (2004) A review of imperative technologies for wastewater treatment 11: hybrid methods. J. Adv. Environ. Res. 8(3/4):501–551.
[09]
Kolaković S, Stefanović D, Milićević D, Trajković S, Milenković S, Kolaković SS., Anđelković L (2013) Effects of reactive filters based on modified zeolite in dairy industry wastewater treatment process. Chemical Industry & Chemical Engineering Quarterly 19(4):583−592.
[10]
Zhang M, Zhang H, Xu D, Han L, Zhang J, Zhang L, Wu W, Tian B (2011) Removal of Phosphate from Aqueous Solution Using Zeolite Synthesized from Fly Ash by Alkaline Fusion Followed by Hydrothermal Treatment. Sep. Sci. Technol. 46(14):2260-2274.
[11]
Zhang BH, Wu D, Wang C, He S, Zhang ZJ, Kong HN (2007) Simultaneous removal of ammonium and phosphate by zeolite synthesized from coal fly ash as influenced by acid treatment. J. Environ. Sci. 19(5):540-545.
[12]
Lin L, Zhongfang L, Wang L, Liu X, Zhang Y, Wan C, Lee DJ, Tay JH (2013) Adsorption mechanisms of high-levels of ammonium onto natural and NaCl-modified zeolites. Separation and Purification Technology 103:15–20.
[13]
Stefanakis AI, Akratos CS, Gikas GD, Tsihrintzis VA (2009) Effluent quality improvement of two pilot-scale, horizontal subsurface flow constructed wetlands using natural zeolite (clinoptilolite). Microporous Mesoporous Mater 124:131–143.
[14]
Tian WH, Wen XH, Qian Y (2004) Using a zeolite medium biofilter to remove organic pollutant and ammonia simultaneously. J. Environ. Sci. 16(1):90-93.
[15]
Qiu L, Zhang S, Wang G, Du M (2010) Performances and nitrification properties of biological aerated filters with zeolite, ceramic particle and carbonate media. Bioresour. Technol. 101(19):7245–7251.
[16]
Ji G, Tong J, Tan Y (2011) Wastewater treatment efficiency of a multi-media biological aerated filter (MBAF) containing clinoptilolite and bioceramsite in a brick-wall embedded design. Bioresour. Technol. 102(2):550–557.
[17]
Syafalni S, Abustan I, Dahlan I, Wah CK, Umar G (2012) Treatment of dye wastewater using granular activated carbon and zeolite filter. Mod. Appl. Sci. 6(2):37–51.
[18]
Erdem E, Karapinar N, Donat R (2004) The removal of heavy metal cations by natural zeolites. J. Colloid Interface Sci. 280:309–314
[19]
Hui KS, Chao CYH, Kot SC (2005) Removal of mixed heavy metal ions in wastewater by zeolite 4A and residual products from recycled coal fly ash. J. Hazard. Mater. 127:89–101.
[20]
Balasubramaniam N, Raja ER, Lalith K, Prabha S (1998) Adsorption Dynamics: Comparison of Adsorption Potentials of Fibrous Keratinous Materials, viz., Human Black and White Hairs. Asian J of Chemistry 10(1):136–145.
[21]
Venkateswarlu P, Venkata Ratnam M, Subba Rao D, Venkateswara Rao M (2007) Removal of chromium from an aqueous solution using Azadirachta indica (neem) leaf powder as an adsorbent. Int. J. Phys. Sci. 2 (8):188–195.
[22]
APHA (American Public Health Association), 1995. Standard methods for the examination of water and wastewater [S]. 19th ed. Washington, D. C.: APHA
[23]
Rand MC, Greenberg AE, Taras MJ (1976) Standard methods for the examination of water and waste water – APHA 14th ed., 42.