Journal of Nanoscience and Nanoengineering
Articles Information
Journal of Nanoscience and Nanoengineering, Vol.1, No.3, Oct. 2015, Pub. Date: Aug. 26, 2015
Model of the Microcomposite Structure of the Internal Areas of Carbon Fibres
Pages: 125-128 Views: 3879 Downloads: 1096
Authors
[01] Belov Petr A., “New Materials, Composites and Nanotechnologies” Engineering Research and Education Center, Bauman Moscow State Technical University, Moscow, Russia.
[02] Kobetz L. P., “New Materials, Composites and Nanotechnologies” Engineering Research and Education Center, Bauman Moscow State Technical University, Moscow, Russia.
Abstract
Specification of the carbon fibres (CF) model is proposed to the development of the Mileyko-Litvinov concept of the microcomposite structure of CF. A classical model defines the CF structure in the form of a fibrillar shell filled with microcomposite. Its matrix represents amorphous carbon of uncertain nature, and the filler - fibrils, with graphite crystallites as its main structural elements. The proposed model is different from the already known models due to accounting for the existence of pores – together with the two known phases of microcomposite – axially oriented fibrils and amorphous (matrix) carbon. It has been established that there are two fundamentally different types of pores: flat and spherical. The flat pores are limited by the surface areas of fibrils and matrix carbon, between which there is no adhesive interaction. The spherical pores are formed by the gaseous products of pyrolysis and carbonisation of CF during the molding stage of the filament. The following experimental data is referenced below in support of the complex four-phase microcomposite structure of the internal areas of the filament.
Keywords
Carbon Fibres, Nano Composites, Defects, Porosity/Voids, Multiscale Modeling
References
[01] Diefendorf R. J., Tokarsky E. High-performance carbon fiber. // Polym. Eng. Sci. 1975, vol. 15, N 3, p. 150-159.
[02] Lemaistre C. W., Diefendorf R. J. Origin of structure in carbonized PAN (polyacrylnitrile) fibers. // SANPE Quart., 1973, vol. 4, N 4, p. 1-6.
[03] Barnet F. R., Noor M. K. Characterisation of carbon fibers by oxygen plasma etch. // Carbon Fibres (Platics and Polim. Conf. Suppl. N 6). The Plastics Institute, London, 1974, p. 32-43.
[04] Tyson C. N. Fracture mtchannisms in carbon fibres derived from PAN in the temperature range 1000-2800C // J. Phys. D: Appl. Phys., vol. 8, 1975. Printed in Great Britain. C 1975.
[05] Fourdeux A., Perret R., Ruland W. General structurel features of carbon fibers // Carbon fibres (Plastics and Polym. Cont. Suppl.№5) The Plastics Institute, London, 1971, p.59-67.
[06] Kobetz L. P., Deev I. S. Carbon fibres: structure and mechanical properties. // Composites science and technology. V.57. 1997. p. 1571-1580.
[07] Litvinov V. B. and others “Structural and mechanical properties of highly durable carbon fibres,” Composites and Nanostructures, 2011. № 3. Pgs. 36–50.
[08] Nelub V. A., Kobetz L. P., Malysheva G.V., Belov Petr A., “Research of the Physical and Chemical Properties of Carbon Fibre Surface the by Raman-Spectroscopy Method, Works II of the International Conference Global Science and Innovation, May 21-22, 2014 vol. II, pgs. 263–268
[09] Bikerman J. J., The physical basis of wetting, Kolloid Z. and Z. Polymer [sic]. 1967. № 1. pgs. 52–56.
[10] Kobetz L. P., Nelub V. A., Belov Petr A., “Study of the Paramagnetic Absorption of Carbon Fibres and Polymer Composites on their Basis,” Research Collection of the International Extramural Scientific-Practical Conference “Topical Questions of Education and Science,” Russia, Tambov, 30 December 2013, section 13, pgs. 64–73.
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